From my limited experience watching anime i'd say the anime with the best ost's in each category of music are:-
Best Fight Music: My Hero Academia
Best Sad Music: Naruto Shippuden
Best Peaceful/Chill/Relaxing Music: K Franchise (K Project/K Missing Kings/ K Return of the Kings) or Samurai Champloo
Every now and then I will do a full listen of the entire Madoka Magica Rebellion soundtrack. There are 45 tracks that are exclusive to the Rebellion movie and they are all amazing. Wonderful pieces of music ranging from soft and gentle to hard and energetic while keeping that eerie vibe throughout. I could be wrong on this but I believe the tracks are listed in order as they happened in the movie too so you sorta get this feeling of beginning to end listening to the whole thing.
Here it is on Youtube although I strongly recommend downloading a 320kbps version to get the best quality.