I often think about Misaka Mikoto and Kamijou Touma from Toaru Majutsu no Index. It's a pretty cute ship, seeing as Touma is the one person (excepting a few other OP characters) that she can't beat in a fight, and she gets super flustered about it.

It is canon that she has a crush on him (pretty sure, anyway), and the Genesis Testament Light Novels are still releasing, so there's hope still.